Monomer Casting Nylon

Papain-Catalyzed Synthesis of Polyglutamate Containing a Nylon Monomer Unit

Peptides have the potential to serve as an alternative for petroleum-based polymers to support a sustainable society. However, they lack thermoplasticity, owing to their strong intermolecular interactions. In contrast, nylon is famous for its thermoplasticity and chemical resistance. Here, we synthesized peptides containing a nylon unit to modify their thermal properties by using papain-catalyz...

Nylon

Non-hazardous biocatalytic oxidation in Nylon-9 monomer synthesis on a 40 g scale with efficient downstream processing.

This paper describes the development of a biocatalytic process on the multi-dozen gram scale for the synthesis of a precursor to Nylon-9, a specialty polyamide. Such materials are growing in demand, but their corresponding monomers are often difficult to synthesize, giving rise to biocatalytic approaches. Here, we implemented cyclopentadecanone monooxygenase as an Escherichia coli whole-cell bi...

Nylon-fiber-induced neutrophil fragmentation.

We have investigated the effects of mechanical elution of neutrophils from nylon-wool fiber (NWF) using the scanning electron microscope and biochemical analysis of elution fractions. We have determined that mechanical removal of neutrophils from nylon-wool fiber disrupts neutrophils adherent to nylon-wool fiber and augments release of granules, release of peripheral cytoplasmic fragments, and ...

The three-dimensional structure of nylon hydrolase and the mechanism of nylon-6 hydrolysis*

From the Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, Hyogo 671-2280; Department of Life Science, Graduate School of Life Science, University of Hyogo, Hyogo 678-1297; RIKEN Harima Institute, SPring-8 Center, Hyogo 679-5148; Institute for Protein Research, Osaka University, Osaka 565-0871, Department of Intelligence Mechanical Technology, G...